VIenna horizontal aNd vertical Distribution OBbservations Of Nitrogen dioxide and Aerosols


Measurement Results

Summer and Fall 2017 - First seasonal NO2 cycle obtained from measurements of both instruments

Since NO2 has strong absorption lines in both the ultraviolet and visible regions of the spectrum, this trace gas can be obtained from measurements of both instruments. There is a clear seasonal cycle of NO2 DSCDs as obtained from the visible MAX-DOAS instrument at α = 3° (green line, left panel). While averaged values are highest in winter, lowest values are observed during summer months.

The NO2 DSCDs retrieved from the UV instrument at α = 1° (green line, right panel), starting in May 2017, show similar values for the summer and fall months - the difference in lowest elevation angles (1° vs. 3°) might be partly compensated by the altitude difference of the two measurement sites (approximately 100 m). Monthly means of NO2 DSCDs observed at α = 30° (black lines) are also in good agreement.


Spring 2017 - Set up of the MAX-DOAS instrument at the BOKU site

The second MAX-DOAS instrument was set up in April 2017 at the BOKU site. The instrument performs measurements between 299 and 399 nm (ultraviolet wavelength range). Currently, six azimuthal viewing directions between 74 and 213° are selected to capture busy roads and industrial areas as well as rather residential areas. The elevation sequence is the same as for the instrument at the VETMED site.

  

After the installation of the MAX-DOAS instrument and selection of viewing directions at the BOKU site, viewing directions at the VETMED site have been modified. Currently, six azimuthal viewing directions are selected at the VETMED site. The settings of both instruments include one azimuthal viewing direction pointing in direction of the other instrument.


Winter 2016/17 - Set up of the MAX-DOAS instrument at the VETMED site and first results

In December 2016, the first MAX-DOAS instrument was set up at the VETMED site. The spectrometer performs measurements between 398 and 534 nm (visible wavelength range). Currently, measurements are obtained in three different viewing directions with a corresponding elevation sequence of 0°, 1°, 2°, 3°, 4°, 5°, 10°, 15°, 30°, and 90° (zenith). Once the second instrument will be set up at the BOKU site, viewing directions of the VETMED instrument will be modified.

After four months of measurements, first analyses were conducted. NO2 DSCDs were derived applying the DOAS analysis.

The diurnal cycle of NO2 DSCDs for different viewing directions and different months was obtained. Two NO2 maxima are found - one in the morning and one in the evening.

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Summer and Fall 2016 - MAX-DOAS and car DOAS zenith-sky measurements in Cabauw, The Netherlands

After successful test measurements in Bremen, the BOKU MAX-DOAS instrument was transferred to Cabauw, The Netherlands, where it participated in the CINDI-2 (Cabauw Intercomparison of Nitrogen Dioxide Measuring Instruments 2) project.

Amongst more than twenty other MAX-DOAS-type instruments, the BOKU MAX-DOAS instrument recorded spectra at predetermined elevation and azimuthal angles. The intensive measurement period lasted two weeks and luckily, contained a couple of ‘golden days’ days.


First results reveal good agreement of NO2 DSCDs when the measurements of the BOKU and IUP-UB MAX-DOAS instruments are compared with each other.

During the CINDI-2 campaign, a couple of Car DOAS measurements were performed on more than five days between the cities Utrecht and Rotterdam. Close to the urban areas, higher amounts of nitrogen dioxide are found - depending on wind direction.


Spring and Summer 2016 - MAX-DOAS set-up and first measurements in Bremen, Germany

After an extensive set-up phase in spring and summer 2016 at the IUP-UB laboratory, first outdoor measurements with the BOKU MAX-DOAS instruments could be performed in mid-August. The instrument recorded spectra at different elevation angles orientated towards west (in accordance with the IUP-UB MAX-DOAS instrument).

First retrieval results of the BOKU MAX-DOAS instrument are compared with NO2 DSCDs of the IUP-UB MAX-DOAS instrument. The agreement of NO2 DSCDs is better for higher than for lower elevation angles. Decreasing agreement towards the horizon might be the result of possible obstacles (e.g. trees) in the viewing direction and/or different field of view of the instruments.


Spring 2016 - Tower DOAS off-axis measurements in Vienna, Austria

Off-axis DOAS measurements on the rotating platform of the Danube Tower in Vienna (about 160 m above ground) were carried out in spring 2016. In the morning of 10 May 2016, nine rounds, each lasting for about 26 minutes, were performed.

After the measurements taken in off-axis direction inside the tower through a glass window, a couple of zenith-sky measurements were recorded from the open terrace (about ten meters below). The DOAS analysis is applied for the retrieval of NO2 DSCDs in the visible spectral range.

First results show a clear spatial variability in the distribution of NO2 on that day. The changing distance of dots from the Danube Tower (DT) is related to changes in light path length due to topography and aerosols.

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Spring and Fall 2015 - Car DOAS zenith-sky measurements in Vienna, Austria

Car DOAS zenith-sky measurements were carried out in spring and fall 2015 within the metropolitan area of Vienna, Austria. A total of three rounds, each having about 100 km distance and lasting for about 1.5 hours, were performed on 10 April 2015 – under clear sky conditions.

Differential slant column densities (DSCDs) of nitrogen dioxide (NO2) are obtained from the spectral measurements by applying the Differential Optical Absorption Spectroscopy (DOAS). The conversion of NO2 DSCDs into tropospheric NO2 vertical column densities (VCDtropo) is based on tropospheric and stratospheric airmass factors (AMFs). Additional data on wind speed and wind direction from nearby weather stations is used to interpret the horizontal and temporal evolution of tropospheric NO2 in Vienna. Moreover, in situ NO2 concentrations from more than a dozen surface stations (provided by the “Amt der Niederösterreichischen Landesregierung“ and “Amt der Wiener Landesregierung“) are utilized and compared with NO2 VCDtropo as derived from our car DOAS measurements.

We identified elevated NO2 pollution from industry nearby an oil refinery and from traffic above busy motorways. NO2 transport events along the Danube River throughout the morning hours could be observed. The comparison between NO2 VCDtropo and in situ NO2 concentrations shows reasonable agreement for this exemplary day.

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